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Water
Hardness
When
natural ground water is exposed to limestone in the
earth, the water may dissolve some of the minerals
in the rock. The concentration and type of minerals
dissolved determines the water hardness and composition.
These minerals are typically calcium and or magnesium
bicarbonates and are referred to as Temporary Hardness
because they will eventually precipitate out of the
water as a scale. Water Hardness is usually measured
in Grains per Gallon expressed as G.P.G.s. A grain
is a measure of weight and equals 1/7000 of a Lb so
1000 gallons of water with 7 GPG of hardness would
contain 1 Lb. of hardness minerals.
Hard
water gets its name from the fact that it can be hard
to deal with and may pose a negative economic impact
on the user. The American Society of Agricultural
Engineers and the Water Quality Association rate water
hardness on a scale in relation to its concentration:
Hardness
Scale
| Term |
Grains/Gallon
|
Mg/Liter
|
| Soft |
<
1.0
|
<
17.0
|
| Slightly
Hard |
1.0
to 3.5
|
17.1
to 60
|
| Moderately
Hard |
3.5
to 7.0
|
60
to 120
|
| Hard |
7.0
to 10.5
|
120
to 180
|
| Very
Hard |
>
10.5
|
>
180
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Excessive
hardness combines with soaps and detergents to create
Hardness Curd. This insoluble curd reduces the effectiveness
of these cleaners ultimately requiring more of the
soap or detergent to do the same job. As water is
evaporated, this curd remains on the surface of skin
and hair often causing irritation or dryness. Calcium
curd also builds up and shortens useful life of laundry
fabrics, appliances and fixtures. Energy efficiency
in water heaters and boilers are minimized by the
scaling of the heat exchange surfaces as the hardness
minerals precipitate out of solution.
Total
Dissolved Solids
Total
Dissolved Solids or TDS refers to the sum of dissolved
mineral content in water. When inorganic materials
are dissolved into water, these minerals form electrically
charged ions and therefore increase the water's ability
to conduct electricity. A special meter to determine
the concentration of these minerals can measure this
conductivity. This measurement is usually expressed
in parts per million or Mg/l. Sea water has approx.
35,000 ppm of total dissolved solids while distilled
water normally has less than 5 ppm. TDS in water affects
its taste and becomes undesirable when the tds level
exceeds 500 mg/l and becomes almost undrinkable over
1000 ppm. In some cases, a water well may be under
the influence of naturally occurring sodium chloride
due to salt deposits within the earth and can lead
to extremely high levels of TDS in the water. The
amount of Total Dissolved Solids in a water supply
can influence the waters ability to be corrosive
or scaling.
Iron
Iron
in water is easy to detect in levels as low as 0.3
mg/l. Inorganic Iron is the second most common element
in the ground and easily dissolves in water. Iron
exceeding 0.3 mg/l may leave behind unsightly stains
that are difficult to remove from fixtures and appliances.
Small amounts of iron in the water affect its flavor
and often add a metallic taste to beverages. Iron
can exist in four different forms in water depending
upon its overall chemistry and its removal from water
is very dependent upon how it exists and in what concentration.
The
four different forms of iron found in the Finger Lakes
Area are:
- Ferrous
-
Ferric
-
Bacterial
-
and Organic
Ferrous
Iron is also referred to as Clear Water Iron because
it is completely dissolved in the water and is invisible
when first drawn. This type of iron will normally
oxidize upon sitting and turn into visible rust to
stain fixtures and laundry.
Ferric
Iron is a rusty sediment or silt that forms when Ferrous
Iron is oxidized. Water with ferric iron present usually
has a slight red or brown color visible when drawn
into a white container.
Iron Bacteria
Bacterial
Iron, or Iron Bacteria is a strain of anaerobic, slime
forming nuisance bacteria that consume iron for metabolism
and trap this iron in a gelatin like mass. Iron Bacteria
are usually easy to detect in the back of a toilet
tank as this provides a good environment for their
growth. Iron Bacteria are not pathogenic "disease
causing" organisms but left unchecked can do
long term damage to water wells, pump systems, piping
and even water treatment equipment. The biomass generated
by these organisms can damage a water well by filling
up the fissures in rock to slow water flow to a crawl
or a stop altogether. The gelatin like biomass created
by these slime-forming bacteria may be periodically
released in a slug causing intermittent discoloration
to the water. Some forms of Iron Bacteria will also
create foul odors in the piping system and water tanks.
Organic
Iron while not very common, is iron that has been
complexed by an organic molecule. This type of iron
can sometimes form a "colloid" which is
a group of tiny particles, each with the same electrical
charge so that they repel each other. This charge
keeps them from grouping together and falling out
of solution making them difficult to remove from water.
Organic Iron can be difficult to detect in the water
because it can be an intermittent problem.
Hydrogen
Sulfide
Hydrogen
Sulfide is a gas in water that gives it the infamous
Rotten Egg Odor. Often referred to as sulfur, hydrogen
sulfide or H2s is easily detectable at 0.2 parts per
million and can be found in our area in concentrations
exceeding 10 PPM or more. H2s is a weak acid when
it is dissolved in the water and can be highly corrosive
to copper, brass, silver and other metals usually
turning them black. H2s in high concentrations will
even penetrate and corrode electrical wiring and equipment
and while rare, high concentrations can be flammable
and are highly toxic to humans.
Sulfate
Reducing Bacteria
Sulfate
Reducing Bacteria are anaerobic slime forming bacteria
that feed on sulfate compounds. The byproduct of their
metabolism is hydrogen sulfide gas. These bacteria
are typically responsible for intermittent sulfur
like odors which can sometimes be detected at low
flowing or least used faucets, water heaters or after
a period of non-use. Like Iron Bacteria, these slime-forming
bacteria can create biomasses that may be responsible
for water well and premature pump failure. Sulfate
or SO4 can occur in ground water or surface water.
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Sulfates
Sulfates
add a medicinal taste to water and can actually act
as a laxative in high concentrations. Sulfates are
Anions or negatively charged ions in water and can
occur naturally in compounds of magnesium, calcium
or sodium sulfate. Sulfates can also be an indicator
of raw sewage or septic contamination and are currently
regulated by the EPA at 250 mg/l as a maximum contaminant
level.
Chlorides
Chlorides,
like sulfates, can occur naturally or be introduced
into water from septic or sewage. Chlorides impart
a bitter taste to water and are suspected of contributing
to hypertension. When water with high chloride content
is softened, the chlorides will become associated
with the potassium or sodium effluent from the softener
to tastesalty. Excessive chloride levels in water
can be corrosive to fixtures and appliances.
Nitrate
Nitrogen does not typically occur naturally in the
Finger Lakes Region and its presence is an indicator
of contamination. Nitrate is associated with agricultural
fertilizers or septic waste and Nitrate/Nitrite combination
levels exceeding 10 mg/l as nitrogen can be highly
toxic to infants. Nitrate is converted by stomach
bacteria to nitrite. Nitrite is an oxygen scavenger
and converts a childs Hemoglobin to methomoglobin,
which is low in oxygen. Methemoglobinemia is also
referred to as Blue Baby Syndrome as the infant actually
turns blue from the lack of oxygen. At risk for Nitrate
contaminations are shallow or dug wells or any well
that is directly or indirectly influenced by agricultural
run-off or possible septic contamination.
Methane
Gas
Methane
Gas can be found in Water Wells around the Finger
Lakes Region and is usually easy to identify by its
cloudy or gassy appearance. Methane or natural gas
is created from the decomposition of organic matter.
Methane can be highly flammable and explosive and
if present, should be removed from the water and safely
vented to the outdoors. Methane Gas often causes faucets
to spit and sputter. In severe cases it is ignitable
right from the faucet. Water with methane gas should
never be chlorinated without removing the methane
first as the combination of methane and chlorine can
form carcinogenic compounds called trihalomethanes
or THMs. The presence of methane gas complicates
water treatment for other common problems due to the
chemical and physical structure of this gas. Iron
and Sulfate Reducing Bacteria are commonly found in
water with methane and will require specialized treatment.
For information on how to treat methane go here.
Colloidal
Clay
Colloidal
Clay is sometimes found in water and makes the water
appear cloudy, muddy or silty. Colloidal Clay gets
its name from the colloids formed by the silt material.
A colloid is a particle with a static charge equal
to the other colloidal particles in the water. Because
like charges repel each other, these particles do
not settle readily and stay suspended. These miniscule
particles are too small to remove by standard filtration
and they must be chemically altered "coagulated"
before they can be filtered. A coagulant test must
be performed to determine the correct chemical and
dosage for successful coagulation and subsequent filtration.
Coliform
Bacteria
Coliform
Bacteria are a member of a very large group of hardy
microorganisms that are used by Health Agencies and
Water Professionals to determine Drinking Water Safety.
Coliform bacteria are used as indicator organisms
because they are not normally found in drinking water
and their presence indicates the potential for possible
"pathogenic " disease causing microbes to
contaminate the water. Coliform Bacteria and even
E.Coli have been found in water wells and lakes should
be taken seriously. If coliform bacteria have been
identified in a properly installed and maintained
water well and E Coli are absent, the well probably
just needs to be shock chlorinated and or cleaned.
If Coliform bacteria return or if E. Coli bacteria
are present, the cause or the problem should be identified
and corrected if possible. If the source of contamination
cannot be identified or corrected, the water should
be treated for disinfection and safety. For more information
on well shocking go here.
Lead
Lead
is a heavy metal that dissolves readily in drinking
water and can cause long term health effects, particularly
in children. The source of lead is likely caused by
the plumbing system itself. Older homes with copper
pipe often have lead soldered joints in the plumbing
or old lead brass fixtures. A proper test for
lead will include a first draw and second draw approach
to determine whether or not lead is in the water supply
or coming from the plumbing.
Lead
is tasteless and has no odor or color. If lead is
present in the water due to the plumbing materials
and remediation of the problem isnt practical,
it may be advisable to treat the water or purchase
bottled water for consumption. Lead in water can be
removed by Ion Exchange Softening or at point of use
with Reverse Osmosis, Distillation or Carbon Block
filtration.
Radon
Radon
is a colorless and odorless gas that can be found
in some well waters. Radon is formed by the natural
decomposition of Radium. The EPA has been working
on establishing a Maximum Contaminant Level (MCL)
for radon in drinking water and the results are expected
in the spring of 2000. Radon in water has been identified
in extremely high levels in some New England States
but I am not aware of any problems with radon in drinking
water in the Finger Lakes at this time. AquaSource
will be conducting an informal study of radon in well
water in the summer of 2000 and will be reporting
our findings to Health Agencies.
Tannins
Tannins
are formed from the decomposition of natural organic
vegetative matter in the soil. While quite rare in
the Western Finger Lakes Region, Tannins can cause
water to have a slight yellowish tint and may cause
staining of laundry and fixtures.
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